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Rudolf Julius Emanuel Clausius Quotes

Browse 5 quotes about Rudolf Julius Emanuel Clausius.

Rudolf Julius Emanuel Clausius Quotes

“I was led to the conclusion that at the most extreme dilutions all salts would consist of simple conducting molecules. But the conducting molecules are, according to the hypothesis of Clausius and Williamson, dissociated; hence at extreme dilutions all salt molecules are completely disassociated. The degree of dissociation can be simply found on this assumption by taking the ratio of the molecular conductivity of the solution in question to the molecular conductivity at the most extreme dilution.”

“So many of the properties of matter, especially when in the gaseous form, can be deduced from the hypothesis that their minute parts are in rapid motion, the velocity increasing with the temperature, that the precise nature of this motion becomes a subject of rational curiosity. Daniel Bernoulli, John Herapath, Joule, Krönig, Clausius, &c., have shewn that the relations between pressure, temperature and density in a perfect gas can be explained by supposing the particles move with uniform velocity in straight lines, striking against the sides of the containing vessel and thus producing pressure. (1860)”

“In despair, I offer your readers their choice of the following definitions of entropy. My authorities are such books and journals as I have by me at the moment. (a) Entropy is that portion of the intrinsic energy of a system which cannot be converted into work by even a perfect heat engine.—Clausius. (b) Entropy is that portion of the intrinsic energy which can be converted into work by a perfect engine.—Maxwell, following Tait. (c) Entropy is that portion of the intrinsic energy which is not converted into work by our imperfect engines.—Swinburne. (d) Entropy (in a volume of gas) is that which remains constant when heat neither enters nor leaves the gas.—W. Robinson. (e) Entropy may be called the ‘thermal weight’, temperature being called the ‘thermal height.’—Ibid. (f) Entropy is one of the factors of heat, temperature being the other.—Engineering. I set up these bald statement as so many Aunt Sallys, for any one to shy at. [Lamenting a list of confused interpretations of the meaning of entropy, being hotly debated in journals at the time.]”

“It is very desirable to have a word to express the Availability for work of the heat in a given magazine; a term for that possession, the waste of which is called Dissipation. Unfortunately the excellent word Entropy, which Clausius has introduced in this connexion, is applied by him to the negative of the idea we most naturally wish to express. It would only confuse the student if we were to endeavour to invent another term for our purpose. But the necessity for some such term will be obvious from the beautiful examples which follow. And we take the liberty of using the term Entropy in this altered sense ... The entropy of the universe tends continually to zero.”